A calorimetric study and modeling of the enthalpy of mixing of Cu-Fe-V melts

被引:0
|
作者
L. A. Dreval’
A. R. Abdulov
P. G. Agraval
M. A. Turchanin
机构
[1] Donbass State Academy of Machine Building,
来源
Russian Journal of Physical Chemistry A | 2010年 / 84卷
关键词
Enthalpy; Versus Versus Versus; Carbonyl Iron; Calorimetric Study; Ternary Interaction;
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学科分类号
摘要
The partial enthalpy of mixing of vanadium in three-component Cu-Fe-V melts was studied at 1873 K along sections with constant xCu/xFe ratios of 3, 1, and 1/3 over the composition range xV = 0–0.55 by high-temperature isoperibolic calorimetry. The Muggianu-Redlich-Kister model was used to describe the concentration dependence of the integral enthalpy of mixing of Cu-Fe-V melts over the whole concentration triangle. The contribution of ternary interaction to the integral enthalpy of mixing of Cu-Fe-V melts was calculated.
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页码:1118 / 1121
页数:3
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