Free radicals from electrochemical reduction of hexahydroquinolones and hexahydroisoquinolones

被引：0
|
作者：
Gavars R. [1 ]
Baumane L. [1 ]
Stradins J. [1 ]
Vigante B. [1 ]
Ozols J. [1 ]
Duburs G. [1 ]
机构：
[1] Latvian Institute of Organic Synthesis
来源：
Chemistry of Heterocyclic Compounds | 1999年 / 35卷 / 7期
关键词：
Organic Chemistry; Free Radical; Dihydropyridine; Electrochemical Reduction; Hyperfine Structure;
D O I：
10.1007/BF02252105
中图分类号：
学科分类号：
摘要：
Electrochemical reduction of 3,5-diethoxycarbonyl- and 3,5-diacetyl-2,6-dimethyl-1,4-dihydropyrdine, hexahydroquinol-5-one, and hexahydroisoquinol-8-one, which contain dihydropyridine moieties, produces free radicals detectable by EPR only for the most easily reduced hexahydroisoquinol-8-ones. The hyperfine structure of the EPR spectra is determined and is consistent with that for the 4,5-dihydropyridine moiety. ©1999 KluwerAcadcmic/Plenum Publishers.
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收藏
页码：809 / 812
页数：3
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