Solid-liquid phase equilibria in the fullerenol-d-CuCl2-H2O system at 25°C

被引：0
|
作者：
K. N. Semenov
I. G. Kanterman
N. A. Charykov
I. V. Murin
A. S. Kritchenkov
机构：
[1] St. Petersburg State University,
[2] ZAO Innovations of Leningrad Institutes and Enterprises,undefined
来源：
Russian Journal of Physical Chemistry A | 2014年 / 88卷
关键词：
solubility diagram; fullerenol; copper(II) chloride; water; simple eutonics;
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学科分类号：
摘要：
Solubility in the ternary fullerenol-d-CuCl2-H2O system at 25°C is studied by means of isothermal saturation in ampoules. It is established that the diagram consists of two branches corresponding to the crystallization of fullerenol-d crystallohydrate and copper(II) chloride dihydrate and contains a single non-variant eutonic point corresponding to the reciprocal saturation with both solid phases. The salting-in effect on the crystallization branch of CuCl2 · 2H2O and the salting-out effect on the crystallization branch of fullerenol-d is revealed.
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页码：1073 / 1075
页数：2
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