Vibrational Spectroscopic Study of [1,2-bis(4-pyridyl)ethane]metal(II) Tetracyanonickelate(II). 2 m-Xylene Clathrates

被引：0
|
作者：
Yüksel Tufan
Nurcan Karacan
Ümmühan Özdemİr
机构：
[1] Erciyes Üniversitesi,Fen
[2] Gazi Üniversitesi,Edebiyat Fak. , Kimya Böl.
来源：
Journal of inclusion phenomena and macrocyclic chemistry | 2001年 / 40卷
关键词：
Hofmann-type clathrate; 1,2-bis(4-pyridyl)ethane; m-xylene inclusion compounds; IR and Raman Spectra;
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学科分类号：
摘要：
Four new Hofmann-type clathrates of the form M(bpa)2Ni(CN)4· 2m-xylene (M = Mn , Fe , Co and Ni; bpa = 1,2-bis(4-pyridyl)ethane) have been synthesized and characterized by vibrational spectroscopy. The M(bpa)2Ni(CN)4 (M = Fe and Co) host structure is similar to the classical Hofmann-type host framework composed of layers of a two dimensional catena-metal tetra-μ-cyanonickelate(II) network, but in M(bpa)2Ni(CN)4 (M = Mn and Ni), the Ni(CN)4 moiety behaves as a bidentate –[NC-Ni(CN)2-CN–]– unit in the host framework.
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页码：275 / 278
页数：3
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