Effect of the anionic composition and pH on the dissolution kinetics of chromium(III) oxide and chromium(III) hydroxide oxide in acids

被引:0
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作者
I. V. Dorovskikh
I. G. Gorichev
V. V. Batrakov
V. V. Kurilkin
A. D. Izotov
机构
[1] Moscow State Pedagogical University,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian University of Peoples’ Friendship,undefined
[3] Russian Academy of Sciences,undefined
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Oxide; Chromium; Hydroxide; Inorganic Chemistry; Experimental Investigation;
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摘要
Based on an experimental investigation of the effects of the pH and anionic composition on the dissolution rate of chromium(III) oxide α-Cr2O3 and chromium(III) hydroxide oxide α-CrOOH and subsequent modeling of the process, it is demonstrated that, depending on the pH, the rate-controlling stage of the dissolution is the CrOH2+ or CrHSO42+ sobulization.
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页码:143 / 151
页数:8
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