Proline-catalyzed aldol reaction of acetone with (R)- and (S)-2,3-O-alkylideneglyceraldehydes

被引：0
|
作者：
Yu. Yu. Kozhemyakin
Yu. Yu. Kozyrkov
机构：
[1] Belarusian State University,
来源：
Russian Journal of Organic Chemistry | 2015年 / 51卷
关键词：
Glyceraldehyde; Enamine; Aldol Reaction; Hydroxy Ketone; Hydroxyacetone;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The results of proline-catalyzed aldol reaction of acetone with O,O′-alkylidene derivatives of glyceraldehyde are determined by the configuration of the chiral center in the aldehyde. The reaction of (S)-2,3-O-alkylideneglyceraldehyde with acetone in the presence of L-proline was characterized by higher diastereoselectivity.
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页码：566 / 568
页数：2
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