Direct rate constant for the reaction of OH radicals with the biofuel molecule ethyl levulinate

被引：0
|
作者：
Mária Farkas
Ádám Illés
Balázs Petri
Sándor Dóbé
机构：
[1] Chemical Research Center of the Hungarian Academy of Sciences,Institute of Materials and Environmental Chemistry
来源：
Reaction Kinetics, Mechanisms and Catalysis | 2011年 / 104卷
关键词：
Second generation biofuels; Levulinic acid ethyl ester; Reaction kinetics; Atmospheric chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Second generation (2G) biofuels are produced from non-edible lignocellulosic biomass providing sustainable alternatives for fossil fuels. The OH reaction rate constant has been determined for the 2G biofuel ethyl levulinate (CH3C(O)CH2CH2C(O)OCH2CH3, ELA) (1) for the first time. The direct reaction kinetic technique of pulsed laser photolysis (PLP) coupled with resonance fluorescence (RF) detection of OH radicals has been used to determine the rate constant value of k1 = (3.43 ± 0.36) × 10−12 cm3 molecule−1 s−1 (298 K), where the error given designates 2σ accuracy. Implications for atmospheric chemistry have been discussed.
引用
收藏
页码：251 / 257
页数：6
相关论文
共 50 条
  • [1] Direct rate constant for the reaction of OH radicals with the biofuel molecule ethyl levulinate
    Farkas, Maria
    Illes, Adam
    Petri, Balazs
    Dobe, Sandor
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2011, 104 (02) : 251 - 257
  • [2] Rate constant for the reaction of OH radicals with dichloromethane
    Villenave, E
    Orkin, VL
    Huie, RE
    Kurylo, MJ
    JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (45): : 8513 - 8517
  • [3] RATE-CONSTANT FOR THE REACTION OF OH RADICALS WITH DIMETHYL SULFIDE
    HSU, YC
    CHEN, DS
    LEE, YP
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1987, 19 (12) : 1073 - 1082
  • [4] Rate constant and branching ratio of the reaction of ethyl peroxy radicals with methyl peroxy radicals
    Zhang, Cuihong
    Li, Chuanliang
    Zhang, Weijun
    Tang, Xiaofeng
    Pillier, Laure
    Schoemaecker, Coralie
    Fittschen, Christa
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (27) : 17840 - 17849
  • [5] DIRECT KINETIC STUDY OF THE REACTION OF OH RADICALS WITH METHYL-ETHYL-KETONE
    Szabo, Emese
    Zuegner, Gabor L.
    Szilagyi, Istvan
    Dobe, Sandor
    Berces, Tibor
    Marta, Ferenc
    REACTION KINETICS AND CATALYSIS LETTERS, 2008, 95 (02): : 365 - 371
  • [6] Direct kinetic study of the reaction of OH radicals with methyl-ethyl-ketone
    Emese Szabó
    Gábor L. Zügner
    István Szilágyi
    Sándor Dóbé
    Tibor Bérces
    Ferenc Márta
    Reaction Kinetics and Catalysis Letters, 2008, 95 : 365 - 371
  • [7] Rate constant for the reaction of OH radicals with isoprene at 298 ± 2K
    Iida, Y
    Obi, K
    Imamura, T
    CHEMISTRY LETTERS, 2002, (08) : 792 - 793
  • [8] Rate constant for the reaction of OH radicals with CH3C(O)Cl determined by direct kinetic method
    Nadasdi, Rebeka
    Szilagyi, Istvan
    Kovacs, Gergely
    Dobe, Sandor
    Berces, Tibor
    Marta, Ferenc
    REACTION KINETICS AND CATALYSIS LETTERS, 2006, 89 (01): : 193 - 199
  • [9] Rate constant for the reaction of OH radicals with CH3C(O)Cl determined by direct kinetic method 
    Rebeka Nádasdi
    István Szilágyi
    Gergely Kovács
    Sándor Dóbé
    Tibor Bérces
    Ferenc Márta
    Reaction Kinetics and Catalysis Letters, 2006, 89 : 193 - 199
  • [10] Rate Constant of the Reaction between CH3O2 Radicals and OH Radicals Revisited
    Assaf, Emmanuel
    Song, Bo
    Tomas, Alexandre
    Schoemaecker, Coralie
    Fittschen, Christa
    JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 120 (45): : 8923 - 8932
12345