Effect of the drying temperature on the structural nonequilibrium of cotton cellulose

被引:0
|
作者
N. A. Yakunin
V. P. Barannikov
机构
[1] Russian Academy of Sciences,Institute of Chemistry of Solutions
来源
Fibre Chemistry | 2011年 / 42卷
关键词
Cellulose; Cotton Fibre; Amorphous Region; Accessible Region; Cotton Cellulose;
D O I
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中图分类号
学科分类号
摘要
A method for quantitatively evaluating the least mobile fraction of moisture sorbed by cotton fibres with the kinetic curves of the change in the desorption process parameters is proposed. The hypothesis that the separated form of the most slowly removed water is localized in sections of the surface layer of crystallites decrystallized on drying is substantiated. Based on an analysis of the temperature curve of the amount of difficult-to-remove moisture, the temperature of the relaxation transition (120-125°C) related to the cooperative mobility of the kinetic elements in the amorphous regions of cellulose was determined
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页码:318 / 321
页数:3
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