Reactions of quinones with organometallic compounds: correlation analysis of substituent effects

被引：0
|
作者：
Yu. A. Kurskii
A. N. Egorochkin
G. A. Abakumov
机构：
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
来源：
Russian Chemical Bulletin | 2017年 / 66卷
关键词：
quinone; organometallic compound; correlation analysis; polarization effect;
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学科分类号：
摘要：
The effects of substituents in lithium, magnesium, zinc, and cadmium organometallic compounds in their reactions with p-benzoquinone and 3,6-di-tert-butyl-o-benzoquinone on the ratio of addition and reduction products were considered. The reduction of quinones follows a homolytic mechanism of single electron transfer. The results of correlation analysis confirmed a suggestion that the addition to quinones followed a nucleophilic (heterolytic) mechanism.
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页码：497 / 501
页数：4
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