Superacidic cyclization of ω-hydroxygeraniol diacetate and ω-hydroxygeraniol benzyl ether acetate

被引：0
|
作者：
V. Kulciţki
N. Ungur
C. Deleanu
P. F. Vlaa
机构：
[1] Academy of Sciences of Republic of Moldova,Institute of Chemistry
[2] Institute of Organic Chemistry of Romanian Academy,undefined
来源：
Russian Chemical Bulletin | 1999年 / 48卷
关键词：
1,8-diacetoxy- and 8-acetoxy-1-benzyloxy-3,7-dimethylocta-2,6-dienes, superacidic cyclization; epimeric; -menth-1-ene-8,9-diols; α-terpineol;
D O I：
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学科分类号：
摘要：
Low-temperature superacidic cyclization of (E,E)-3,7-dimethylocta-2,6-diene-1,8-diol (ω-hydroxygeraniol) diacetate and (E,E)-8-acetoxy-1-benzyloxy-3,7-dimethylocta-2,6-diene leads to the same mixtures of two diastereomeric 9-acetoxy-8-hydroxy-p-menth-1-enes epimeric at the C(8) atom.
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页码：136 / 138
页数：2
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