Mechanism of metallization of ionic crystals by pressure

被引：0
|
作者：
S. S. Batsanov
机构：
[1] Center for High Dynamic Pressures,
来源：
Russian Journal of Physical Chemistry | 2006年 / 80卷
关键词：
Experimental Data; Physical Chemistry; Compressibility; Metal Cation; Interatomic Distance;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Experimental data on the compressibility of the high-pressure phases of a number of ionic crystals were used to calculate the energies of compression corresponding to the energies of atomization of these substances. It was found that interatomic distances in the compressed substances are equal to the sum of radius of the metal cation and the covalent radius of the nonmetal atom. The mechanism of the metallization of ionic crystals, in particular, the sources of delocalized electrons, was discussed.
引用
收藏
页码：135 / 138
页数：3
相关论文
共 50 条
  • [1] Mechanism of metallization of ionic crystals by pressure
    Batsanov, S. S.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2006, 80 (01): : 135 - 138
  • [2] DECORATION MECHANISM OF IONIC CRYSTALS
    TROFIMOV, VI
    CHALYKH, AE
    LUKYANOV.VM
    SOVIET PHYSICS SOLID STATE,USSR, 1969, 11 (06): : 1408 - &
  • [3] THE GROWTH MECHANISM OF IONIC CRYSTALS
    EGLI, PH
    JOHNSON, LR
    ZIMMERMAN, W
    ACTA CRYSTALLOGRAPHICA, 1957, 10 (12): : 838 - 838
  • [4] The mechanism behind SnO metallization under high pressure
    Pesach, Asaf
    Nguyen, Long
    Gorelli, Federico A.
    Bini, Roberto
    Hevroni, Refael
    Nikolaevsky, Mark
    dos Santos, Antonio M.
    Tulk, Christopher A.
    Molaison, Jamie J.
    Shuker, Reuben
    Melchior, Aviva
    Caspi, El'ad N.
    Salem, Ran
    Makov, Guy
    Sterer, Eran
    RESULTS IN PHYSICS, 2022, 39
  • [5] THE MECHANISM OF IONIC POLYMERIZATION IN FORMALDEHYDE CRYSTALS
    BAZILEVSKII, MV
    GERASIMOV, GN
    PETROCHENKO, SI
    KHIMICHESKAYA FIZIKA, 1984, 3 (02): : 162 - 168
  • [6] INTERPRETATION OF MECHANISM OF IONIC POLYMERIZATION IN CRYSTALS
    BAZILEVSKII, MV
    GERASIMOV, GN
    KITROSSKII, LN
    PETROCHENKO, SI
    TIKHOMIROV, VA
    KINETICS AND CATALYSIS, 1981, 22 (05) : 889 - 895
  • [7] Pressure dependence of ionic polarizabilities in crystals
    Batana, A
    Bruno, JAO
    Monard, MC
    INORGANIC MATERIALS, 2005, 41 (03) : 293 - 297
  • [8] Pressure dependence of ionic polarizabilities in crystals
    Monard, MC
    Bruno, JAO
    Faour, J
    Batana, A
    COMPUTERS & CHEMISTRY, 2001, 25 (05): : 429 - 438
  • [9] Pressure dependence of ionic polarizabilities in crystals
    A. Batana
    J. A. O. Bruno
    M. C. Monard
    Inorganic Materials, 2005, 41 : 293 - 297
  • [10] METALLIZATION OF IONIC CLUSTERS
    RAJAGOPAL, G
    BARNETT, RN
    LANDMAN, U
    PHYSICAL REVIEW LETTERS, 1991, 67 (06) : 727 - 730
12345