Hydroxylation of benzene in the system vanadium(V)-hydrogen peroxide-acetic acid

被引：0
|
作者：
N. I. Rudakova
M. V. Klyuev
Yu. G. Erykalov
D. N. Ramazanov
机构：
[1] Ivanovo State University,
来源：
Russian Journal of General Chemistry | 2006年 / 76卷
关键词：
General Chemistry; AcOH; Isoalkanes; Sodium Vanadate; Dihydroxybenzene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Hydroxylation of benzene in acetic acid at 323 K was studied in the presence of a sodium orthovanadate catalyst. With hydrogen peroxide as aqueous solution, the yield of phenol was 12–14%. With hydrogen peroxide generated from dry sodium peroxide, the yield of phenol could be improved to 21–23%. The apparent decomposition rate constants of hydrogen peroxide in acetic acid are presented.
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页码：1407 / 1409
页数：2
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