Thiocyanation of N-aryl, N-acetyl, and N-[arylsulfonylimino(methyl)methyl] derivatives of 1,4-benzoquinone monoimine

被引:0
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作者
S. A. Konovalova
A. P. Avdeenko
O. P. Ledeneva
A. L. Yusina
V. V. Pirozhenko
O. V. Shishkin
G. V. Palamarchuk
机构
[1] Donbass State Engineering Academy,Institute of Organic Chemistry
[2] Ukraine Engineering and Pedagogical Academy,Institute of Single Crystals
[3] National Academy of Sciences of Ukraine,undefined
[4] National Academy of Sciences of Ukraine,undefined
[5] Karazin Kharkov National University,undefined
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关键词
Thiocyanate; LUMO Energy; Phenylsulfonyl; Potassium Thiocyanate; Compound Xiii;
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摘要
N-[arylsulfonylimino(methyl)methyl] derivatives of 1,4-benzoquinone monoimine with alkyl substituents in the quinoid ring have been synthesized and their spectral characteristics were determined. The thiocyanation of N-aryl, N-acetyl, and N-[arylsulfonylimino(methyl)methyl] derivatives of 1,4-benzoquinone monoimine depending on the LUMO energy of the initial quinone monoamine affords derivatives of benzo[d][1,3]oxathiol-2-ones and benzo[d]oxazole-2(3H)-thiones.
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页码:635 / 646
页数:11
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