Synthesis and properties of new halogen-substituted 2-pentafluorophenyl-2-trifluoromethyl-1,3-dioxolanes

被引：0
|
作者：
L. M. Popova
机构：
[1] St. Petersburg State Technological University of Plant Polymers,
来源：
Russian Journal of Applied Chemistry | 2009年 / 82卷
关键词：
Fluorine Atom; Hydrogen Fluoride; Dioxolane; Stretch Vibration Band; Cyclohexyl Methyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
2-Pentafluorophenyl-2-trifluoromethyl-1,3-dioxolane was prepared by cyclization of octafluoroacetophenone with 2-chloroethanol under the conditions of base catalysis. Successive chlorination of the product yielded the corresponding 4,4,5,5-tetrachloro derivative. Fluorination of the latter in the SbF3/SbCl5 system yields 4,5-dichloro-4,5-difluoro-2-pentafluorophenyl-2-trifluoromethyl-1,3-dioxolane.
引用
收藏
页码：2156 / 2160
页数：4
相关论文
共 50 条
  • [1] Synthesis and properties of new halogen-substituted 2-pentafluorophenyl-2-trifluoromethyl-1,3-dioxolanes
    Popova, L. M.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2009, 82 (12) : 2156 - 2160
  • [2] Synthesis and properties of new halogen-substituted 2-Pentafluorophenyl-2- trifluoromethyl-1,3-dioxolanes
    Popova, L.M.
    Russian Journal of Applied Chemistry, 2009, 82 (12): : 2156 - 2160
  • [3] SYNTHESIS OF 2-ALKOXY-1,3-DIOXOLANES AND 2-ARYLOXY-1,3-DIOXOLANES
    SOULIER, J
    FARINES, M
    AUTHIER, RM
    FOURNIER, M
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1976, 13 (05) : 1125 - 1128
  • [4] Synthesis and antimuscarinic activity of derivatives of 2-substituted-1,3-dioxolanes
    Marucci, Gabriella
    Angeli, Piero
    Brasili, Livio
    Buccioni, Michela
    Giardinà, Dario
    Gulini, Ugo
    Piergentili, Alessandro
    Sagratini, Gianni
    MEDICINAL CHEMISTRY RESEARCH, 2005, 14 (05) : 274 - 296
  • [5] Synthesis and Antimuscarinic Activity of Derivatives of 2-Substituted-1,3-Dioxolanes
    Gabriella Marucci
    Angeli Piero
    Livio Brasili
    Michela Buccioni
    Dario Giardinà
    Ugo Gulini
    Alessandro Piergentili
    Gianni Sagratini
    Medicinal Chemistry Research, 2005, 14 : 274 - 296
  • [6] Synthesis and antimuscarinic activity of derivatives of 2-substituted-1,3-dioxolanes
    Marucci, Gabriella
    Angeli, Piero
    Brasili, Livio
    Buccioni, Michela
    Giardina, Dario
    Gulini, Ugo
    Piergentili, Alessandro
    Sagratini, Gianni
    Franchini, Silvia
    MEDICINAL CHEMISTRY RESEARCH, 2005, 14 (06) : 309 - 331
  • [7] Synthesis and Antimuscarinic Activity of Derivatives of 2-Substituted-1,3-Dioxolanes
    Gabriella Marucci
    Piero Angeli
    Livio Brasili
    Michela Buccioni
    Dario Giardinà
    Ugo Gulini
    Alessandro Piergentili
    Gianni Sagratini
    Silvia Franchini
    Medicinal Chemistry Research, 2005, 14 : 309 - 331
  • [8] SYNTHESIS OF SOME SUBSTITUTED 1,3-DIOXOLANES
    KUZNETSO.NV
    MYRSINA, RA
    UKRAINSKII KHIMICHESKII ZHURNAL, 1970, 36 (10): : 1050 - &
  • [9] THE PHARMACOLOGICAL PROPERTIES OF SOME 2-SUBSTITUTED-4-HYDROXYMETHYL-1,3-DIOXOLANES
    BERGER, FM
    BOEKELHEIDE, V
    TARBELL, DS
    SCIENCE, 1948, 108 (2812) : 561 - 562
  • [10] ONE-STEP SYNTHESIS OF SUBSTITUTED 2-ARYL-2-BROMOALKYL-1,3-DIOXOLANES
    SVOBODA, J
    PALECEK, J
    DEDEK, V
    MOSTECKY, J
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1984, 49 (06) : 1515 - 1520
12345