Synthesis and properties of [1,4]diazepino[6,5-b]indoles

被引：0
|
作者：
N. A. Lantsetti
S. Yu. Ryabova
L. M. Alekseeva
A. S. Shashkov
V. G. Granik
机构：
[1] State Scientific Center of the Russian Federation “Organic Intermediate Products and Dyes Institute” (NIOPIK),Russian Academy of Sciences
[2] N. D. Zelinsky Institute of Organic Chemistry,undefined
来源：
Russian Chemical Bulletin | 2002年 / 51卷
关键词：
3-arylamino-2-formylindole; [1,4]diazepino[6,5-; ]indole; -oxide; deoxidation; pyrido[3,2-; ]indole; pyrimido[5,4-; ]indole;
D O I：
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中图分类号：
学科分类号：
摘要：
1-Aryl-2-oxo-1,2,3,6-tetrahydro[1,4]diazepino[6,5-b]indole N-oxides were synthesized based on 3-(N"-aryl-N"-chloroacetyl)amino-2-formylindoles. Deoxidation of 2-oxo-1-phenyl-1,2,3,6-tetrahydro[1,4]diazepino[6,5-b]indole N-oxide afforded 1,2,3,6-tetrahydro- and 1,2,3,4,5,6-hexahydro[1,4]diazepino[6,5-b]indole derivatives. A new approach to the synthesis of pyrido[3,2-b]indole and pyrimido[5,4-b]indole derivatives was developed.
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页码：506 / 512
页数：6
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