Morphology and Characterization of Epoxy-acrylate Composite Particles

被引：0
|
作者：
Shao-Xiang Li
Wen-Fang Wang
Lu-Mei Liu
Guang-Ye Liu
机构：
[1] Qingdao University of Science & Technology,Department of micropolymer materials of science and engineering
[2] Qingdao University of Science & Technology,Department of materials science and engineering
来源：
Polymer Bulletin | 2008年 / 61卷
关键词：
Emulsion Polymerization; Transmission Electron Microscope Micrographs; Butyl Acrylate; Butyl Acrylate; Seed Emulsion Polymerization;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Epoxy-acrylate sample was prepared by two-stage feed emulsion polymerization. Gel permeation chromatography (GPC) and Ultraviolet-Visible (UV-Vis) spectra indicated the acrylic and styrene monomer were grafted onto epoxy resin. Transmission electron microscope (TEM) showed that epoxy-acrylate composite particles with different epoxy resin content stained by pH1.5 phosphotungstic acid (PTA) had an obvious core-shell structure, with styrene-acrylate as the core and epoxy resin as the shell. TEM micrographs also showed the acrylate cores concentrically or eccentrically were positioned inside epoxy resin shells, which was consonant with the particle structures designed. But the Epoxy Resin/Methyl Methacrylate (EP/MMA) particles showed a strange quadrangle-like structure and Epoxy Resin/Methyl Methacrylate/ Butyl Acrylate (EP/MMA/BA) particles showed a hexagon-like structure, which were different from the normal particle structures.
引用
收藏
页码：749 / 757
页数：8
相关论文
共 50 条
  • [1] Morphology and Characterization of Epoxy-acrylate Composite Particles
    Li, Shao-Xiang
    Wang, Wen-Fang
    Liu, Lu-Mei
    Liu, Guang-Ye
    POLYMER BULLETIN, 2008, 61 (06) : 749 - 757
  • [2] Synthesis and characterization of epoxy-acrylate composite latex
    Pan, GR
    Wu, LM
    Zhang, ZQ
    Li, D
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 83 (08) : 1736 - 1743
  • [3] ESR study of photopolymerization of epoxy-acrylate oligomers
    Sadykov, RA
    Gatiyatullina, GV
    Battalov, EM
    Prochulkhan, YA
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2003, 76 (04) : 629 - 633
  • [4] ESR Study of Photopolymerization of Epoxy-Acrylate Oligomers
    R. A. Sadykov
    G. V. Gatiyatullina
    E. M. Battalov
    Yu. A. Prochukhan
    Russian Journal of Applied Chemistry, 2003, 76 : 629 - 633
  • [5] Highly Accelerated Synthesis of Epoxy-Acrylate Resin
    Mohtadizadeh, F.
    Zohuriaan-Mehr, M. J.
    JOURNAL OF POLYMER MATERIALS, 2013, 30 (04): : 461 - 469
  • [6] TESTS SHOW EPOXY-ACRYLATE IS RESISTANT TO CHEMICALS SOLVENTS
    MAY, CA
    NEWEY, HA
    MATERIALS PROTECTION, 1965, 4 (10): : 47 - &
  • [7] The Sensitization of Aliphatic Epoxy Photopolymerization in Epoxy-Acrylate Interpenetrating Polymer Networks
    Samoilenko, Tetiana
    Iarova, Nataliia
    Menzheres, Halyna
    Brovko, Oleksandr
    FRENCH-UKRAINIAN JOURNAL OF CHEMISTRY, 2014, 2 (01): : 5 - 9
  • [8] Simultaneous interpenetrating polymer networks based on epoxy-acrylate combinations
    Baidak, AA
    Liegeois, JM
    Sperling, LH
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1997, 35 (12) : 1973 - 1984
  • [9] Preparation and characterization of dimer fatty acid epoxy-acrylate resin hybrid emulsion for photocurable coatings
    Lian, Shengyuan
    Xu, Kai
    Liu, Hongbo
    Gui, Xuefeng
    Zhang, Tian
    COLLOID AND POLYMER SCIENCE, 2019, 297 (09) : 1199 - 1211
  • [10] Preparation and characterization of dimer fatty acid epoxy-acrylate resin hybrid emulsion for photocurable coatings
    Shengyuan Liang
    Kai Xu
    Hongbo Liu
    Xuefeng Gui
    Tian Zhang
    Colloid and Polymer Science, 2019, 297 : 1199 - 1211
12345