Platinum nanoparticles on carbon nanomaterials with graphene structure as hydrogenation catalysts

被引:0
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作者
S. D. Kushch
N. S. Kujunko
B. P. Tarasov
机构
[1] Russian Academy of Sciences,Institute of Chemical Physics Problems
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关键词
Fullerene; Nitrobenzene; Hydrogen Absorption; Graphene Structure; Platinum NANOPARTICLES;
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摘要
Carbon nanomaterials with graphene structure (single- and multiwall nanotubes and nanofibers) after oxidizing by a mixture of sulfuric and nitric acids and presumable introducing of carboxyl groups can be used as carrying agents of hydrogenation catalysts. Platinum in a concentration which should not exceed 10 wt % can be fixed using H2PtCl6 as a precursor in presence of an organic base. Catalysts based on these nanomaterials with the average size of platinum particles 6–8 nm exceed in activity the Pt/C catalyst with the size of platinum particles 65–70 nm, but are inferior to catalysts based on fullerene black with the average size of platinum particles 3–4 nm.
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页码:706 / 710
页数:4
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