Dependence of the solution and transfer enthalpies of DL-α-alanyl-DL-α-asparagine on the composition of water-amide binary solvents at 298.15 K

被引：0

作者：

V. G. Badelin

V. I. Smirnov

机构：

[1] Russian Academy of Sciences,Institute of Solution Chemistry

来源：

Russian Journal of Physical Chemistry A | 2011年 / 85卷

关键词：

peptides; enthalpies of solution and transfer; water-organic mixtures;

D O I：

暂无

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学科分类号：

摘要：

Solution enthalpies of DL-α-alanyl-DL-α-asparagine (AlaAsn) in water-formamide, water-N-methylformamide, water-N,N-dimethylformamide, and water-N,N-dimethylacetamide mixtures were measured in the range of amide mole fractions x2 = 0–0.3. The standard enthalpies of solution (ΔsolH°) and transfer (ΔtrH°) of AlaAsn from water to the binary solvent and enthalpy coefficients of pair-wise interactions (hxy) of AlaAsn with amide molecules were calculated. The influence of the composition of the water-organic mixture on the enthalpy characteristics of AlaAsn is discussed. It is shown that the enthalpy characteristics of solution and transfer of AlaAsn are related to the structure of amides.

引用

共 23 条

[1] Dependence of the solution and transfer enthalpies of DL-α-alanyl-DL-α-asparagine on the composition of water-amide binary solvents at 298.15 K
Badelin, V. G.
Smirnov, V. I.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (06) : 944 - 947
[2] Enthalpies of solution of DL-α-alanyl-DL-α-asparagine in aqueous alcohols at 298.15 K
Smirnov, Valeriy I.
Badelin, Valentin G.
THERMOCHIMICA ACTA, 2011, 512 (1-2) : 55 - 58
[3] The Enthalpy of Solution of DL-α-Alanyl-DL-α-Valine Depending on the Composition of Water-Alcohol Binary Solvents at 298.15 K
Smirnov, V. I.
Badelin, V. G.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 82 (12) : 2069 - 2073
[4] The enthalpy of solution of DL-α-alanyl-DL-α-valine depending on the composition of water-alcohol binary solvents at 298.15 K
V. I. Smirnov
V. G. Badelin
Russian Journal of Physical Chemistry A, Focus on Chemistry, 2008, 82 : 2069 - 2073
[5] Enthalpies of solution of DL-α-Alanyl-DL-α-Valine in aqueous solution of amides at 298.15 K
Smirnov, Valeriy I.
Badelin, Valentin G.
THERMOCHIMICA ACTA, 2009, 485 (1-2) : 72 - 75
[6] The thermochemical characteristics of solution of DL-α-alanylglycine and DL-α-alanyl-DL-α-alanine in water-organic solvent mixtures at 298.15 K
Smirnov, V. I.
Mezhevoi, I. N.
Badelin, V. G.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 81 (08) : 1245 - 1249
[7] The thermochemical characteristics of solution of DL-α-alanylglycine and DL-α-alanyl-DL-α-alanine in water-organic solvent mixtures at 298.15 K
V. I. Smirnov
I. N. Mezhevoi
V. G. Badelin
Russian Journal of Physical Chemistry A, 2007, 81 : 1245 - 1249
[8] Influence of the Composition of (H2O + SDS) Mixtures on the Interaction Energy of dl-α-Alanyl-dl-α-Valine and dl-α-Alanyl-dl-α-Norleucine with SDS Micelles at T = 298.15 K
V. I. Smirnov
V. G. Badelin
V. P. Barannikov
M. S. Kurbatova
Journal of Solution Chemistry, 2019, 48 : 1309 - 1317
[9] Influence of the Composition of (H2O + SDS) Mixtures on the Interaction Energy of dl-α-Alanyl-dl-α-Valine and dl-α-Alanyl-dl-α-Norleucine with SDS Micelles at T=298.15 K
Smirnov, V. I.
Badelin, V. G.
Barannikov, V. P.
Kurbatova, M. S.
JOURNAL OF SOLUTION CHEMISTRY, 2019, 48 (8-9) : 1309 - 1317
[10] The enthalpies of solution of DL-α-alanine in water-alcohol mixtures at 298.15 K
Smirnov, VI
Mezhevoi, IN
Badelin, VG
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2004, 78 (02): : 214 - 217

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