Synthesis of the iron phthalocyaninate radical cation μ-nitrido dimer and its interaction with hydrogen peroxide

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作者
E. S. Grishina
A. S. Makarova
E. V. Kudrik
S. V. Makarov
O. I. Koifman
机构
[1] Ivanovo State University of Chemical Technology,Institute of Macroheterocyclic Compounds
[2] Russian Academy of Sciences,Krestov Institute of Solution Chemistry
关键词
iron μ-nitrido phthalocyaninate; radical cation; catalysis; hydrogen peroxide;
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摘要
The iron phthalocyaninate μ-nitrido dimer radical cation, as well as the μ-nitrido dimer complexes of iron phthalocyaninate, was found to have high catalytic activity in the oxidation of organic compounds. It was concluded that this compound is of interest as a model of active intermediates—catalase and oxidase enzymes.
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页码:704 / 706
页数:2
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