Electron transmission through organized organic thin films studied by discrete initial electron kinetic energies

被引:0
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作者
A. Haran
R. Naaman
G. Ashkenasy
A. Shanzer
T. Quast
B. Winter
I.V. Hertel
机构
[1] Department of Chemical Physics,
[2] Weizmann Institute of Science,undefined
[3] 76100 Rehovot,undefined
[4] Israel,undefined
[5] Department of Organic Chemistry,undefined
[6] Weizmann Institute of Science,undefined
[7] 76100 Rehovot,undefined
[8] Israel,undefined
[9] Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie,undefined
[10] Postfach 1107,undefined
[11] 12474 Berlin,undefined
[12] Germany,undefined
关键词
PACS. 79.60.Dp Adsorbed layers and thin films - 73.20.At Surface states, band structure, electron density of states - 73.61.Ph Polymers; organic compounds;
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摘要
Synchrotron radiation (SR) pulses are used to eject electrons from a gold substrate covered with organized organic thin films (OOTF) in order to investigate their transmission probability through the OOTF as a function of the electron initial kinetic energy. By variation of the SR photon energy within a few eV above the Au-4f binding energy levels we controlled the initial kinetic energy of the substrate electrons. The observed oscillations in the transmission probability for porphyrin-based films as a function of the kinetic energy is argued to be due to effects of band structure above the vacuum level in the well-ordered molecular adsorbate. We also present valence photoemission spectra (PES) of different type OOTF and demonstrate how their coverage of the substrate affects the PES.
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页码:445 / 451
页数:6
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