EPR Study of Covalent Bond in Transition Metal Complexes

被引：0
|
作者：
V. I. Murav'ev
机构：
[1] Research and Production Enterprise “Izmeritel'”,
来源：
Russian Journal of Coordination Chemistry | 2005年 / 31卷
关键词：
Physical Chemistry; Inorganic Chemistry; Approximation Method; Metal Complex; Covalent Bond;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The results of a study of a covalent bond in the anitibonding and bonding states of d1 and d9 complexes obtained by analyzing the EPR and optical data are presented. The nature of the electron density delocalization in some of the complexes is discussed. The effect of the charge-transfer states on the covalent bond structure is considered. The vibronic effect on the ground state function is discussed. The electronic distributions determined from EPR spectra by different approximation methods are compared.
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页码：609 / 618
页数：9
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