Synthesis and photochromic properties of fulgides and fulgimides, 5-alkoxybenzo[b]furan derivatives

被引：0
|
作者：
V. P. Rybalkin
N. I. Makarova
S. Yu. Pluzhnikova
L. L. Popova
A. V. Metelitsa
V. A. Bren’
V. I. Minkina
机构：
[1] Russian Academy of Sciences,Southern Research Center
[2] Southern Federal University,Research Institute of Physical and Organic Chemistry
来源：
Russian Chemical Bulletin | 2014年 / 63卷
关键词：
benzo[; ]furan; fulgide; fulgimide; synthesis; photochromism;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New heterocyclic fulgides, 3-[1-(5-alkoxy-2-methylbenzo[b]furan-3-yl)ethylidene]-4-(2-propylidene)dihydro-2,5-furandiones, and fulgimides, 1-(2-dimethylaminoethyl)-3-[(5-methoxy-2-methylbenzo[b]furan-3-yl)ethylidene]-4-(2-propylidene)dihydro-2,5-pyrroledione and 1-benzyl-3-[(5-methoxy-2-methylbenzo[b]furan-3-yl)ethylidene]-4-(2-propylidene)dihydro-2,5-pyrroledione, were synthesized. Electron spectroscopy and 1H NMR spectroscopy were used to establish that all the compounds obtained have Z-configuration and exhibit photo-chromic properties with high stability to photodegradation in solutions. Cyclic photoisomers of fulgides possess fluorescent properties and thermal stability.
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页码：1780 / 1784
页数：4
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