Thermal stability and oxygen resistance of polypropylene composites with fullerene/montmorillonite hybrid fillers

被引:0
|
作者
Qiunan Chen
Ting Sai
Zhengping Fang
Zhenghong Guo
机构
[1] Zhejiang University,Lab of Polymer Material and Engineering, Ningbo Institute of Technology
[2] Shanghai University,School of Materials Science and Engineering
来源
Journal of Thermal Analysis and Calorimetry | 2021年 / 146卷
关键词
Fullerene; Polypropylene; Montmorillonite; Thermal stability; Anti-oxidation;
D O I
暂无
中图分类号
学科分类号
摘要
Silane coupling agent (KH-550) was used to connect fullerene (C60) with montmorillonite (MMT) to prepare C60-decorated MMT hybrid (C60-Si-MMT), and the mass ratio of C60 to MMT was about 1:5. PP/C60-Si-MMT composites with the C60-Si-MMT loading that 3.0% by mass were prepared via melt compounding. TG and DSC results showed that C60-Si-MMT could remarkably enhance the onset degradation temperature (Tonset) and the maximum decomposition temperature (Tmax) of PP to 287.9 °C and 394.7 °C, respectively. And the oxidative induced time of PP also greatly extended to 14.4 min. Rheological investigation results and thermogravimetric analysis coupled to Fourier transform infrared spectroscopy (TG-IR) showed that good dispersive states of C60-Si-MMT in matrix cause C60 trap free radicals and MMT restrict the segment movement of macromolecular chain more effectively.
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页码:1383 / 1392
页数:9
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