Reaction of hexachlorobutadiene with sodium methoxide

被引：0
|
作者：
V. A. Egorov
F. A. Gimalova
L. S. Khasanova
M. S. Miftakhov
机构：
[1] Ufa Research Center of the Russian Academy of Sciences,Institute of Organic Chemistry
来源：
Russian Chemical Bulletin | 2015年 / 64卷
关键词：
hexachlorobutadiene; methanol; α,β-unsaturated esters; ortho esters; hydrolysis;
D O I：
暂无
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学科分类号：
摘要：
Hexachlorobutadiene reacts with MeONa in refluxing methanol to give (Z)-4,4-dimethoxy2-oxobut-3-enoic acid and 2,4,4-trichloro-1,1,1,3-tetramethoxybut-2-ene, which were converted to methyl (Z)-4,4-dimethoxy-2-oxobut-3-enoate and methyl (Z)-2,4,4-trichloro-3methoxybut-2-enoate upon treatment with CH2N2 and acid hydrolysis, respectively.
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页码：355 / 358
页数：3
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