Synthesis of levulinic acid from fructose using Amberlyst-15 as a solid acid catalyst

被引：0
|
作者：
Pham Anh Son
Shun Nishimura
Kohki Ebitani
机构：
[1] Japan Advanced Institute of Science and Technology,School of Materials Science
来源：
Reaction Kinetics, Mechanisms and Catalysis | 2012年 / 106卷
关键词：
Amberlyst-15; Solid acid catalyst; Fructose; Levulinic acid;
D O I：
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学科分类号：
摘要：
Levulinic acid was obtained from fructose over solid acid catalysts under mild reaction conditions in water. The reaction was carried out at different temperatures and amounts of catalysts to find the best reaction conditions. Among tested heterogeneous catalysts, Amberlyst-15 gave the highest LA yield (52%) with the lowest HMF yield (below 3%) under optimum conditions. Levulinic acid was isolated from the mixture after reaction by rotary vacuum evaporator with 47% isolated yield. The recycling experiments showed that Amberlyst-15 exhibited good activity even after 5 runs, though the LA yield gradually decreased from 52 to 30%.
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页码：185 / 192
页数：7
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