Synthesis of 14 h-naphtho[1',2':5,6][1,3]oxazino-[3,2-a]benzimidazole, a new heterocyclic system

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作者
V. A. Osyanin
D. V. Osipov
Yu. N. Klimochkin
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[1] Samara State Technical University,
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2-methylsulfanylbenzimidazole; -methylenequinones; 14 H-naphtho[1',2':5,6][1,3]oxazino-[3,2-; ]benzimidazoles; Mannich bases; cascade reactions;
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摘要
The previously unreported 14 H-naphtho[1',2':5,6][1,3]oxazino[3,2-a]benzimidazole heterocyclic system was synthesized by the condensation of 1-dimethylaminomethyl-2-naphthols and 2-methyl-sulfanylbenzimidazole. A highly reactive o-methylenequinone derivative of naphthalene is proposed as an intermediate in this reaction.
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