Molecular co-crystals of carboxylic acids, part 29. The effect of competitive interactions on adduct formation involving 2-aminopyrimidine: the crystal structure of the 1∶1 adduct of 2-aminopyrimidine with indole-2-carboxylic acid

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作者
Daniel E. Lynch
Tariq Latif
Graham Smith
Karl A. Byriel
Colin H. L. Kennard
机构
[1] Coventry University,School of Natural and Environmental Sciences
[2] Queensland University of Technology,School of Physical Sciences
[3] The University of Queensland,Department of Chemistry
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Hydrogen-bonding; co-crystal; X-ray crystal structure; 2-aminopyrimidine;
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摘要
The crystal structure of the 1∶1 adduct of 2-aminopyrimidine with indole-2-carboxylic acid has been determined by single crystal X-ray diffraction, revealing a novel interactive mode. The utility of 2-aminopyrimidine in formation of stable hydrogen-bonded networks with carboxylic acids is discussed and the modes of interaction are reviewed.
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页码:567 / 575
页数:8
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