Thermal Behaviour of the N-donor Adducts of Metal Saccharinates: I. 2,2'-bipyridine saccharinato complexes of Co(II), Ni(II), Cu(II), Zn(II) and Pb(II)

被引：0
|
作者：
P. Naumov
V. Jordanovska
O. Grupče
B. Boyanov
G. Jovanovski
机构：
[1] ‘Sv. Kiril i Metodij’ University,Institute of Chemistry, Faculty of Science
[2] Plovdiv University,Faculty of Chemistry
来源：
Journal of Thermal Analysis and Calorimetry | 2001年 / 65卷
关键词：
2,2′-bipyridine; -donor adducts; saccharinates; thermal decomposition;
D O I：
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学科分类号：
摘要：
The adducts of Co, Ni, Cu, Zn and Pb saccharinates with 2,2'-bipyridine were synthesized and their thermal behaviour in the 20–1000°C temperature interval in a static air atmosphere was investigated. Regardless of the coordination, the decomposition starts with dehydration and proceeds with removal of the bipyridine ligand(s). The resulting metal(II) saccharinates adopt characteristic two-step decomposition, the first step being the SO2 release. Their stability was found tobe metal-dependent. The thermal decomposition pathways were correlated with the existing structural data about the compounds.
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页码：59 / 67
页数：8
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