Oxidation of Iron and Nickel with 3,5-Di-tert-butyl-1,2-benzoquinone in Coordinating Solvents

被引：0
|
作者：
S. V. Maslennikov
I. A. Aivaz'yan
I. V. Spirina
V. K. Cherkasov
V. P. Maslennikov
机构：
[1] Lobachevsky Nizhni Novgorod State University,Research Institute of Chemistry
[2] Russian Academy of Sciences,Razuvaev Institute of Organometallic Chemistry
来源：
Russian Journal of General Chemistry | 2005年 / 75卷
关键词：
Oxidation; Iron; Entropy; Nickel; Enthalpy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The final products of oxidation of iron and nickel with 3,5-di-tert-butyl-1,2-benzoquinone in DMSO were identified, and the formal-kinetics relationships of the process were elucidated. The apparent equilibrium constants, enthalpies, and entropies of adsorption of the reactants on the metal surfaces and the rate constants and activation energies of the reactions were determined.
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页码：1576 / 1578
页数：2
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