Intercalation of Methylamine into the Protonated Forms of Layered Perovskite-Like Oxides HLnTiO4 (Ln = La and Nd)

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作者
O. I. Silyukov
S. A. Kurnosenko
I. A. Zvereva
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[1] St. Petersburg State University,
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layered titanate; methylamine; intercalation; organic-inorganic compounds; hydrothermal microwave synthesis;
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摘要
New hybrid organic-inorganic derivatives HLnTiO4 · CH3NH2 (Ln = La and Nd) are obtained via the intercalation of methylamine into the interlayer space of protonated layered perovskite-like titanates HLnTiO4. The existence of three stable methylamine derivatives, namely, α-, β-, and γ-forms, is found for each of the titanates. The thermal stability of the obtained intercalation products is studied and their structural parameters are determined.
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页码:428 / 432
页数:4
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