Physicochemical and Analytical Properties of Surfactant-Modified Redox Reagents of the Diphenylamine Series

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作者
N. A. Burmistrova
S. P. Mushtakova
S. N. Shtykov
L. F. Kozhina
V. N. Rodnikova
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[1] Saratov State University,Department of Chemistry
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Nitrogen; Spectroscopy; Surfactant; Aqueous Solution; Titration;
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摘要
The effect of the nature and concentration of aqueous solutions of surfactants (ions and micelles) on the spectrochemical, acid-base and redox properties of organic reagents of the diphenylamine series bearing different substituents in phenyl rings and at the bridging nitrogen atom was studied by potentiometric titration and absorption and photoluminescence spectroscopy. The surfactant micelle–reagent binding constants were determined, and the correlation between the binding constants and the above-mentioned properties was analyzed.
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页码:651 / 657
页数:6
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