A van der Waals free energy in electrolytes revisited

被引:0
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作者
B. Jancovici
机构
[1] Laboratoire de Physique Théorique,
[2] Université de Paris-Sud,undefined
[3] Unité Mixte de Recherche 8627 CNRS,undefined
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Polymer; Physical Chemistry; Neural Network; Thin Film; Free Energy;
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摘要
A system of three electrolytes separated by two parallel planes is considered. Each region is described by a dielectric constant and a Coulomb fluid in the Debye-Hückel regime. In their book Dispersion Forces, Mahanty and Ninham have given the van der Waals free energy of this system. We rederive this free energy by a different method, using linear response theory and the electrostatic Maxwell stress tensor for obtaining the dispersion force.
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页码:1 / 4
页数:3
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