p-toluenesulfonyl esters of perfluorinated tertiary alcohols:: crystal structure determination of the absolute configuration of C6F5(CF3)2COSO2C6H4CH3

被引：1

作者：

Krumm, B ^{[1
]}

Vij, A ^{[1
]}

Kirchmeier, RL ^{[1
]}

Shreeve, JM ^{[1
]}

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 89卷 / 01期

关键词：

perfluorinated tertiary alcohols; p-toluenesulfonyl esters; p-toluenesulfonyl chloride;

D O I：

10.1016/S0022-1139(98)00080-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Selected perfluorinated tertiary alcohols can be reacted with p-toluenesulfonyl chloride to form their p-toluenesulfonyl esters C6F5(CF3)(2)COSO2C6H4CH3 (1), CF3C6F4OC6F4(C3F7)(C8F17)COSO2C6H4CH3 (2) and (CF3C6F4OC6F4)(2)(C7F15)COSO2C6H4CH3 (3). The absolute configuration of 1 is established by X-ray diffraction. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：19 / 22

页数：4

共 50 条

[1] p-Toluenesulfonyl esters of perfluorinated tertiary alcohols: crystal structure determination of the absolute configuration of C6F5(CF3)2COSO2C6H4CH3
Krumm, B.
Vij, A.
Kirchmeier, R. L.
Shreeve, J. M.
Journal of Fluorine Chemistry, 89 (01):
[2] REACTIVITY OF CYCLOPALLADATED COMPOUNDS .7. SYNTHESES OF METALLOBICYCLIC COMPOUNDS AND THEIR REACTIONS WITH ACETYLENES - X-RAY CRYSTAL AND MOLECULAR-STRUCTURES OF THE COMPOUNDS [(NME2CH2C6H4)PD(C(CF3)=C(CF3)(C6H4CH2NME2))] AND [((NME2CH2C6H4)C(CF3)=C(CF3))PD(C(CF3)=C(CF3)(CH2C9H6N))]
ARLEN, C
PFEFFER, M
BARS, O
GRANDJEAN, D
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (08): : 1535 - 1544
[3] 2 STABLE THIOSULFURANES, CF3(CF3S)S[OC(CF3)3]2 AND C6F5(C6F5S)S[OC(CF3)3]2
MIR, QC
BABB, DP
SHREEVE, JM
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (14) : 3961 - 3961
[4] New or improved syntheses of the polyfluoroalcohols HOC(cyclo-C6H11)2(CF3), HO(cyclo-C6H11)(CF3)2, and HOC(Ar)(CF3)2 (Ar=4-C6H4(t-Bu), 2,4,6-C6H2(CF3)3, 4-Si(i-Pr)3-2,6-C6H2(CF3)2, 3,5-C6H3(CH3)2), and 2-C6H4(C(OH)(CF3)2)
Barbarich, TJ
Nolan, BG
Tsujioka, S
Miller, SM
Anderson, OP
Strauss, SH
JOURNAL OF FLUORINE CHEMISTRY, 2001, 112 (02) : 335 - 342
[5] The hydrogenation reaction of [Ru3(CO)10(C6F5)2P(CH2)2P(C6F5)2]: Migration of a C6F5 group from a phosphorus to a ruthenium atom. X-ray crystal structures of [Ru3(CO)9(μ-H){μ2-(C6F5)PCH2CH2P(C6F5)2}], [Ru3(CO)7(μ-H)3(η1-C6F5){μ3-PCH2CH2P(C6F5)2}] and [Ru3(CO)8(μ-H)2{μ3-PCH2CH2P(C6F5)2}]
Sanchez-Cabrera, Gloria
Leyva, Marco A.
Zuno-Cruz, Francisco J.
Hernandez-Cruz, Maria G.
Rosales-Hoz, Maria J.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (13) : 1949 - 1958
[6] Preparation and characterization of [Hg{P(C6F5)2}2], [Hg{(μ-P(C6F5)2)W(CO)5}2], and [Hg{(μ-P(CF3)2)W(CO)5}2] and the X-ray crystal structure of [Hg{(μ-P(C6F5)2)W(CO)5}2]•2DMF
Hoge, B
Herrmann, T
Thösen, C
Pantenburg, I
INORGANIC CHEMISTRY, 2003, 42 (17) : 5422 - 5428
[7] A NOVEL OLEFIN BRIDGED DINUCLEAR ARYLPALLADIUM COMPOUND - X-RAY CRYSTAL-STRUCTURE OF [NME2CH2C6H4PD-MU-(C(CF3)=C(CF3)C(CF3)=C-(CF3))PDCH(SIME3)C6H4NME2]
MAASSARANI, F
PFEFFER, M
LEBORGNE, G
WEHMAN, E
VANKOTEN, G
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (25) : 8002 - 8004
[8] The electron-poorphosphines P{C6H3(CF3)2-3,5}3 and P(C6F5)3 do not mimic phosphites as ligands for hydroformylation.: A comparison of the coordination chemistry of P{C6H3(CF3)2-3,5}3 and P(C6F5)3 and the unexpectedly low hydroformylation activity of their rhodium complexes
Clarke, ML
Ellis, D
Mason, KL
Orpen, AG
Pringle, PG
Wingad, RL
Zaher, DA
Baker, RT
DALTON TRANSACTIONS, 2005, (07) : 1294 - 1300
[9] SYNTHESIS AND STRUCTURE OF (CH3)2ASC(CF3)=C(CF3)AS(CH3)2W(CO)2BR2P(C6H5)3
MANOCHA, SK
MIHICHUK, LM
BARTON, RJ
ROBERTSON, BE
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 722 - 725
[10] Stabilization of the P(CF3)2- and P(C6F5)2- ions by coordination to pentacarbonyl tungsten:: Structures of [18-crown-6-K]P(CF3)2, [18-crown-6-K][W{P(CF3)2}(CO)5], and [18-crown-6-K][{W(CO)5}2{μ-P(C6F5)2}]•THF
Hoge, B
Thösen, C
Herrmann, T
Pantenburg, I
INORGANIC CHEMISTRY, 2003, 42 (11) : 3633 - 3641

← 1 2 3 4 5 →