Transition-metal-catalyzed benzylation of arenes and heteroarenes

被引：147

作者：

Mertins, K ^{[1
]}

Iovel, I ^{[1
]}

Kischel, J ^{[1
]}

Zapf, A ^{[1
]}

Beller, M ^{[1
]}

机构：

[1] Univ Rostock eV, IfOK, Leibniz Inst Organ Katalyse, D-18055 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期

关键词：

arenes; benzylation; Friedel-Crafts reaction; iridium; platinum;

D O I：

10.1002/anie.200460666

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Friedel-Crafts-type benzylation of various aromatic and heteroaromatic compounds with benzylic acetates, alcohols, and carbonates was promoted under mild reaction conditions by a series of Rh, Ir, Pd, and Pt catalysts (see scheme; R1 = H, Me; R2 = H, Cl, MeO; R3 = H, Ac, CO2Me). The desired products were obtained in high yields and with high selectivities.

引用

页码：238 / 242

页数：5

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