Quinone alkylation using organocadmium reagents: A general synthesis of quinols

被引：17

作者：

Aponick, A ^{[1
]}

McKinley, JD ^{[1
]}

Raber, JC ^{[1
]}

Wigal, CT ^{[1
]}

机构：

[1] Lebanon Valley Coll, Dept Chem, Anneville, PA 17003 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 63卷 / 08期

关键词：

D O I：

10.1021/jo972300d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of p-benzoquinone with organocadmium reagents yield quinols, the result of quinone carbonyl monoalkylation. The reactions proceed in good yield and are devoid of bisaddition and hydroquinone byproducts. Quinone alkylations using this method show general applicability to p-benzoquinone as well as extended quinone systems using primary alkyl, secondary alkyl, and aryl reagents.

引用

页码：2676 / 2678

页数：3

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