Thermal analysis of calix[4]resorcinarene complexes with secondary and tertiary amines

被引:7
|
作者
Utzig, E [1 ]
Pietraszkiewicz, O [1 ]
Pietraszkiewicz, M [1 ]
机构
[1] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
amine; calix[4] resorcinarene; complexes; DSC; TG;
D O I
10.1007/s10973-004-0463-y
中图分类号
O414.1 [热力学];
学科分类号
摘要
Tetra-n-undecylcalix[4] resorcinarene forms solid adducts with secondary and tertiary amines. Thermal decomposition of these complexes was investigated by means of thermogravimetry (TG) and differential scanning calorimetry (DSC). It was found that deamination of complexes occurs as multi-step process. The stoichiometry of complexes was evaluated on the basis of TG studies and total heats of deamination were calculated from DSC measurements.
引用
收藏
页码:973 / 980
页数:8
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