Polyaniline-maleicacid-dodecylhydrogensulfate Salt as Sensor Material for Toxic Gases

被引:14
|
作者
Palaniappan, Srinivasan [1 ]
Saravanan, Chandrasekaran [1 ]
机构
[1] Indian Inst Chem Technol, Organ Coatings & Polymers Div, Hyderabad 500607, Andhra Pradesh, India
关键词
sensors; conducting polymers; emulsion polymerization; THIN-FILM; AMMONIA GAS; CONDUCTING POLYMERS; DOPED POLYANILINE; AQUEOUS AMMONIA; ADSORPTION; ELECTRODE; HUMIDITY; STATE; CO;
D O I
10.1002/app.32347
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This article reports the results of novel polyaniline material as gas sensor, capable of operating at room temperature for toxic gases. Polyaniline-maleicacid-dodecylhydrogensulfate salt (PANI-MA-DHS) was prepared by emulsion polymerization pathway, which is soluble in N, N-dimethyl formamide. PANI-MA-DHS was coated on a ceramic bead by simple brush coating method and used as sensor material. The resistance change of PANT-MA-DHS material for NH3, CO2, SO2, and H2S gases at different concentrations (10, 100, 1000, and 10,000 ppm level) was monitored for sensor characteristics. The stability of the polyaniline material under continuous exposure of gas level from 10 to 10,000 ppm was also studied. This novel gas sensor material has advantages such as excellent sensing ability, low cost, fast regeneration time (similar to 1-2 min), simple experimental setup, and operable at room temperature. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 118: 518-524, 2010
引用
收藏
页码:518 / 524
页数:7
相关论文
共 50 条
  • [1] A novel polyaniline-maleicacid-dodecylhydrogensulfate salt: Soluble polyaniline powder
    Palaniappan, Srinivasan
    Amarnath, Chellachamy Anbalagan
    REACTIVE & FUNCTIONAL POLYMERS, 2006, 66 (12): : 1741 - 1748
  • [2] Polyaniline-dodecylhydrogensulfate-acid salt: synthesis and characterization
    Palaniappan, S
    Amarnath, CA
    MATERIALS CHEMISTRY AND PHYSICS, 2005, 92 (01) : 82 - 88
  • [3] Thermal stability and structure of electroactive polyaniline-fluoroboric acid-dodecylhydrogensulfate salt
    Palaniappan, Srinivasan
    Devi, Subbarao Lakshmi
    POLYMER DEGRADATION AND STABILITY, 2006, 91 (10) : 2415 - 2422
  • [4] Polyaniline as a gas-sensor material
    Sengupta, Partha Pratim
    Barik, Satyananda
    Adhikari, Basudam
    MATERIALS AND MANUFACTURING PROCESSES, 2006, 21 (03) : 263 - 270
  • [5] Fluorinated porous silicon as sensor material for environmentally toxic gases: a first-principles study
    Eduardo Santana, Jose
    de Santiago, Francisco
    Miranda, Alvaro
    Antonio Perez, Luis
    Salazar, Fernando
    Trejo, Alejandro
    Cruz-Irisson, Miguel
    MATERIALS ADVANCES, 2021, 2 (03): : 1072 - 1082
  • [6] Application of conducting polyaniline as sensor material for ammonia
    Dhawan, SK
    Kumar, D
    Ram, MK
    Chandra, S
    Trivedi, DC
    SENSORS AND ACTUATORS B-CHEMICAL, 1997, 40 (2-3) : 99 - 103
  • [7] A novel polyaniline-fluoroboric acid-dodecylhydrogensulfate salt: versatile reusable polymer based solid acid catalyst for organic transformations
    Palaniappan, S
    John, A
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 233 (1-2) : 9 - 15
  • [8] A Distributed Sensor System for Detection of Toxic and Hazardous Gases
    Eliza, Sazia A.
    Olah, Robert
    Dutta, Achyut K.
    SENSORS, AND COMMAND, CONTROL, COMMUNICATIONS, AND INTELLIGENCE (C3I) TECHNOLOGIES FOR HOMELAND SECURITY AND HOMELAND DEFENSE IX, 2010, 7666
  • [9] Design and fabrication of sensor structures for the measurement of toxic gases
    Gonzalez-Chavarri, J.
    Castro-Hurtado, I.
    Mandayo, G. G.
    Castano, E.
    PROCEEDINGS OF THE 2013 SPANISH CONFERENCE ON ELECTRON DEVICES (CDE 2013), 2013, : 107 - 109
  • [10] Chenio-optical sensor for toxic gases detection
    Caldararu, F
    Ionescu, C
    Vasile, A
    Caldararu, M
    2005 28TH INTERNATIONAL SPRING SEMINAR ON ELECTRONICS TECHNOLOGY, 2005, : 55 - 59