Deprotonated 2,3:5,6-dibenzo-7-aza bicyclo[2.2.1]hepta-2,5-diene as a nitrido nitrogen source by anthracene elimination:: Synthesis of an iodide(nitride)chromium(VI) complex

被引：0

作者：

Mindiola, DJ ^{[1
]}

Cummins, CC ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 07期

关键词：

azides; chromium; nitrides; nitrogen; N ligands;

D O I：

10.1002/(SICI)1521-3773(19980420)37:7<945::AID-ANIE945>3.0.CO;2-X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Instead of azides, which can be explosive and poorly soluble in nonpolar solvents, azabicyclohepatadienes can be used to synthesize nitrides. The reaction of diiodide 1 with the lithium amide 3 provides the red nitride 2 in 60% yield with loss of lithium iodide and anthracene. The remaining iodo ligand in 2 can undergo an exchange reaction with lithium amide 3, but no more anthracene is released.

引用

页码：945 / 947

页数：3

共 8 条

[1] SYNTHESIS OF 2,3-BIS(ACETOXYMETHYL)BICYCLO[2.2.1]HEPTA-2,5-DIENE AND ITS USE IN PALLADIUM-CATALYZED ELIMINATION
MUCHOW, G
BRUNEL, JM
MAFFEI, M
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JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (04): : 852 - 855
[2] (1S, 4R)-1,2,3,4,7,7-hexachloro-5,6-bis(chloromethyl)bicyclo[2.2.1]hepta-2,5-diene
Wilson, Zakiya S.
Davila, Alfonso
McLaughlin, Mark L.
Watkins, Steven F.
Fronczek, Frank R.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O303 - O305
[3] Crystal structure of [(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]diiodoplatinum(II), PtI2(C7H8)
Ha, Kwang
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (02): : 319 - 320
[4] CATIONIC-ETA-3-R,2,3-ETA-5-5,6-2R-BICYCLO[2.2.1]HEPTA-2,5-DIENE-R-YL (R = CH2, CHCH3) COMPLEXES OF RHODIUM AND IRON
CHIZHEVSKY, IT
KORIDZE, AA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 153 (02) : C28 - C30
[5] PLATINUM-CARBON SIGMA-BONDS WITH HINDERED ROTATION - CHLORO(2-ALKOXY-NAPHTH-1-YL)(2,3,5,6-ETA-4-BICYCLO[2.2.1]HEPTA-2,5-DIENE) PLATINUM(II) - SYNTHESIS AND STRUCTURE
DEBAERDEMAEKER, T
WEISEMANN, C
BRUNE, HA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 350 (01) : 91 - 99
[6] PHOSPHINOSULFOXIDE RHODIUM COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURE, AND CATALYTIC CHEMISTRY OF [(2,3,5,6-ETA)-BICYCLO[2.2.1]-HEPTA-2,5-DIENE][P,O-DIPHENYL(PHENYLSULPHINYLMETHYL)-PHOSPHINE]RHODIUM(I)TRIFLUOROMETHANESULPHONATE AND ASYMMETRIC ANALOGS
ALCOCK, NW
BROWN, JM
EVANS, PL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 356 (02) : 233 - 247
[7] PREPARATION OF (S,S)-1,2-BIS(tert-BUTYLMETHYLPHOSPHINO)ETHANE ((S,S)-t-Bu-BISP*) AS A RHODIUM COMPLEX [Rhodium(1+), [(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene] (S,S)-1,2-bis(M, -butymethylphosphino)ethane, trafluoroborate(1-)]
Crepy, Karen V. L.
Imamoto, Tsuneo
ORGANIC SYNTHESES, 2005, 82 : 22 - +
[8] HEPTACYCLO[5.5.1.1(4,10).0(2,6).0(3,11).0(5,9).0(8,12)]TETRADECANE-13,14-BIS(SPIRO-1'-CYCLOPENTANE) - A NEW C22H28 NONACYCLIC CAGE HYDROCARBON - IMPROVED SYNTHESIS OF BICYCLO[2.2.1]HEPTA-2,5-DIENE-7-SPIRO-1'-CYCLOPENTANE
MARCHAND, AP
WU, AH
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (03): : 396 - 398

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