Synthesis of molecular vanadium(III) phosphonates

被引：81

作者：

Khanra, Sumit ^{[1
]}

Kloth, Marc ^{[1
]}

Mansaray, Hassanatu ^{[1
]}

Muryn, Christopher A. ^{[1
]}

Tuna, Floriana ^{[1
]}

Sanudo, E. Carolina ^{[1
]}

Helliwell, Madeleine ^{[1
]}

McInnes, Eric J. L. ^{[1
]}

Winpenny, Richard E. R. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 29期

基金：

英国工程与自然科学研究理事会;

关键词：

magnetic properties; phosphonate ligands solvothermal; synthesis; vanadium; X-ray diffraction;

D O I：

10.1002/anie.200701115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

All in the family: Organophosphonate complexes of high-valent vanadium are common, but their VIII analogues are few and far between. Reaction of VCl3 precursors and phosphonates under solvothermal conditions leads to a family of corresponding vanadium (III)-based phosphonates, including the layered {VIII12(VIVO)} cluster shown in the picture (V green, P purple, O red, C black). Preliminary magnetic studies are also reported. (Figure Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5568 / 5571

页数：4

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