Selenoxide elimination and [2,3]sigmatropic rearrangement

被引：0
|
作者：
Nishibayashi, Y
Uemura, S
机构：
[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
来源：
ORGANOSELENIUM CHEMISTRY: MODERN DEVELOPMENTS IN ORGANIC SYNTHESIS | 2000年 / 208卷
关键词：
selenoxide elimination; 2,3]sigmatropic rearrangement; selenoxide; selenimide; selenium ylide;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recent advances of the following four types of asymmetric reactions using organoselenium compounds are reviewed: selenoxide elimination, [2,3]sigmatropic rearrangement via selenoxides, [2,3]sigmatropic rearrangement via selenimides, and [2,3]sigmatropic rearrangement via selenium ylides. In all reactions, the preparation or the intervention of optically active organoselenium compounds having a chiral center on the selenium atom such as selenoxides, selenimides, and selenium ylides is shown to be essential to obtain the chiral organic compounds with high stereoselectivity.
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页码：201 / 233
页数：33
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