Sequential Selective Extraction Procedures for the Study of Heavy Metals in Soils, Sediments, and Waste Materialsa Critical Review

被引:156
|
作者
Hass, Amir [2 ,3 ,4 ]
Fine, Pinchas [1 ]
机构
[1] Agr Res Org, Volcani Ctr, Dept Soil Sci & Plant Nutr, Inst Soil Water & Environm Sci,Minist Agr, IL-50250 Bet Dagan, Israel
[2] ARS, USDA, Appalachian Farming Syst Res Ctr, Beaver, WV USA
[3] W Virginia State Univ, Gus R Douglass Land Grant Inst, Institute, WV 25112 USA
[4] W Virginia State Univ, Agr & Environm Res Stn, Institute, WV USA
关键词
biosolids; iron oxide; metal partitioning; metal solubility; metal speciation; ARID-ZONE SOILS; MOLECULAR-SIZE DISTRIBUTION; AMMONIUM OXALATE SOLUTIONS; SEWAGE-SLUDGE; ORGANIC-MATTER; TRACE-ELEMENTS; SODIUM-HYPOCHLORITE; CONTAMINATED SOILS; CHEMICAL FRACTIONATION; HYDROGEN-PEROXIDE;
D O I
10.1080/10643380802377992
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The authors review selected protocols of sequential selective extraction procedure that are used to characterize the geochemical distribution of heavy metals in soils, wastes, and sediments. They discuss the development of earlier protocols, their modifications, and the extent to which a given protocol pertains to different conditions. Emphasis is given to the considerations that led to a choice of reagents for each step and to their order in the sequence. Published studies are used as case studies to critically evaluate the implied geochemical components of operationally defined extraction steps. Also assessed are possible effects of subsequent extraction steps and conditions on the selective dissolution of the solid components and their operational definitions.
引用
收藏
页码:365 / 399
页数:35
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