Rhodium(I) complexes of unsymmetrical diphosphines: efficient and stable methanol carbonylation catalysts

被引:54
|
作者
Carraz, CA
Ditzel, EJ
Orpen, AG
Ellis, DD
Pringle, PG
Sunley, GJ
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] BP Chem, Hull Res & Technol Ctr, Hull HU12 8DS, N Humberside, England
关键词
D O I
10.1039/b002802i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rhodium complexes of unsymmetrical diphosphines of the type Ph2PCH2CH2PAr2 are catalysts for the carbonylation of methanol; several features of the catalysis are reminiscent of iridium carbonylation catalysts.
引用
收藏
页码:1277 / 1278
页数:2
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