Theoretical study on the mechanism of electrochemical reduction reactions of honokiol

被引：0

作者：

Sun, CK

Gong, SY

Li, ZH ^{[1
]}

Ma, SY

Li, QL

机构：

[1] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China

[2] Qujing Normal Coll, Dept Chem, Qujing 655000, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2000年 / 21卷 / 06期

关键词：

honokiol; electrochemical reaction; mechanism; AM1; method;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of electrochemical reduction reaction of 2-(3-allyl-4-hydroxyl)-phenyl-4-allylphenol, also named honokiol, has been studied by using the semi-empirical molecular orbital AM1 and PM3 methods. The results show that these reduced positions of honokiol molecule are two double bonds of o-allyl and p-allyl groups, and the o-allyl group is reduced first, then the p-allyl group, The honokiol gets 4e and 4H(+), and the two allyl groups are saturated in the reduction process, The calculated results are in good agreement with experimental facts.

引用

页码：912 / 917

页数：6