Oxidative coupling of methane in solid oxide fuel cell tubular membrane reactor with high ethylene yield

被引：33

作者：

Liu, Kefeng ^{[1
]}

Zhao, Jing ^{[2
]}

Zhu, Di ^{[2
]}

Meng, Fei ^{[2
]}

Kong, Fanhua ^{[1
]}

Tang, Yongchun ^{[2
]}

机构：

[1] PetroChina Petrochem Res Inst, Beijing 100195, Peoples R China

[2] Power Environm Energy Res Inst, 738 Arrow Grand Circle, Covina, CA 91722 USA

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 96卷

关键词：

OCM; SOFC; Methane; Ethylene; Membrane reactor; Mn-Ce-Na2WO4; CONVERSION; CATALYSTS; PERFORMANCE; ETHANE; AROMATICS; ALKALI; ANODE;

D O I：

10.1016/j.catcom.2017.03.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Mn-Ce-Na2WO4/SiO2 catalyst integrated solid oxide fuel cell tubular membrane reactor design is developed for oxidative coupling of methane (OCM). The OCM reaction carried out using the tubular membrane reactor establishes both superb hydrocarbon selectivity and outstanding ethylene-to-ethane ratio over the conventional fixed bed OCM or the button cell reactor. A remarkable performance of 60.7% methane conversion with 41.6% C2+ selectivity, 5.8 ethylene-to-ethane ratio and 19.4% ethylene yield is achieved using the tubular membrane reactor and the Mn-Ce-Na2WO4/SiO2 catalyst, demonstrating considerable advantages over conventional OCM. (C) 2017 Published by Elsevier B.V.

引用

页码：23 / 27

页数：5

共 50 条

[1] Oxidative coupling of methane in a solid oxide fuel cell reactor
Jiang, Y
Yentekakis, IV
Makri, M
Vayenas, CG
PROCEEDINGS OF THE FIFTH INTERNATIONAL SYMPOSIUM ON SOLID OXIDE FUEL CELLS (SOFC-V), 1997, 97 (40): : 235 - 243
[2] Oxidative coupling of methane in a solid oxide membrane reactor
Guo, XM
Hidajat, K
Ching, CB
Chen, HF
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (09) : 3576 - 3582
[3] Direct oxidative coupling of methane into ethylene in a catalyst-enhanced planar solid oxide fuel cell stack reactor
He, Yeheng
Meng, Fei
Xing, George
Liu, Kefeng
Lou, Shujie
Xiao, Haicheng
Tang, Yongchun
PHYSICS OPEN, 2024, 20
[4] Simulation of a solid oxide fuel cell for oxidative coupling of methane
Guo, XM
Hidajat, K
Ching, CB
CATALYSIS TODAY, 1999, 50 (01) : 109 - 116
[5] Oxidative coupling of methane in a solid oxide fuel cell.
Hidajat, K
Guo, XM
Ching, CB
Chen, HF
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 46 - PETR
[6] Oxidative coupling of methane to ethylene: Development of membrane reactor
Zein, SHS
Mohamed, AR
Zabidi, NAM
Bhatia, S
ADVANCES IN MALAYSIAN ENERGY RESEARCH 2000, 2001, : 317 - 328
[7] Oxidative coupling of methane in solid oxide fuel cells
Guo, XM
Hidajat, K
Ching, CB
Chen, HF
3RD WORLD CONGRESS ON OXIDATION CATALYSIS, 1997, 110 : 683 - 692
[8] Study on oxidative coupling of methane in oxygen permeable tubular membrane reactor
Wang, HH
Cong, Y
Yang, WS
Lin, LW
CHINESE JOURNAL OF CATALYSIS, 2003, 24 (03) : 169 - 174
[9] Multi-objective optimization in solid oxide fuel cell for oxidative coupling of methane
Quddus, Mohammad R.
Zhang, Yan
Ray, Ajay K.
CHEMICAL ENGINEERING JOURNAL, 2010, 165 (02) : 639 - 648
[10] SELECTIVE OXIDATIVE COUPLING OF METHANE WITH MEMBRANE REACTOR
NOZAKI, T
YAMAZAKI, O
OMATA, K
FUJIMOTO, K
CHEMICAL ENGINEERING SCIENCE, 1992, 47 (9-11) : 2945 - 2950

← 1 2 3 4 5 →