Syntheses and post-functionalization of tri-substituted polyalkoxohexavanadates containing tris(alkoxo) ligands

被引：29

作者：

Hu, Xunliang ^{[1
]}

Xiao, Zicheng ^{[1
]}

Huang, Bo ^{[1
]}

Hu, Xiaokang ^{[1
]}

Cheng, Min ^{[1
]}

Lin, Xinjun ^{[1
]}

Wu, Pingfan ^{[1
]}

Wei, Yongge ^{[1
,2
]}

机构：

[1] Hubei Univ Technol, Hubei Prov Key Lab Green Mat Light Ind, Inst POM Based Mat, Wuhan 430068, Peoples R China

[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 26期

基金：

中国国家自然科学基金;

关键词：

POLYOXOMETALATE-ORGANIC HYBRID; ALKOXIDE ANION CLUSTERS; STRUCTURAL-CHARACTERIZATION; VALENCE; POLYOXOVANADATES; CATALYSTS;

D O I：

10.1039/c7dt01543g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new synthetic approach to tri-substituted trisalkoxy-hexavanadate clusters containing different organic groups was developed in this work. Four mixed-valence or fully reduced POV hybrids were synthesized and structurally characterized, including an amino-containing derivative of hexavanadate, Na-2[(V3V3O10)-V-IV-O-V{NH2C(CH2O)(3)}(3)] (1). Furthermore, a novel mixed-valence POV hybrid was prepared via the amidation of 1, indicating that 1 can be used as an excellent building block for the design and synthesis of mixed-valence POV functional materials.

引用

页码：8505 / 8513

页数：9

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