Phase behavior of binary homopolymer/diblock blends: Temperature and chain length dependence

被引：74
|
作者：
Janert, PK [1 ]
Schick, M [1 ]
机构：
[1] Univ Washington, Dept Phys, Seattle, WA 98195 USA
来源：
MACROMOLECULES | 1998年 / 31卷 / 04期
关键词：
D O I：
10.1021/ma971093g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The phase behavior of binary blends of A homopolymer and symmetric AB diblock copolymer is studied within mean-held theory. The occurrence of lamellar, hexagonal, and body-centered-cubic phases is examined in the weak to intermediate segregation regime and over a wide range of homopolymer length relative to that of the diblock. This ratio is found to be a crucial parameter for the topology of the phase diagram. Several different classes of behavior are established, and comparisons are made with experiment.
引用
收藏
页码：1109 / 1113
页数：5
相关论文
共 50 条
  • [1] Phase behavior of binary blends of diblock copolymer/homopolymer confined in spherical nanopores
    Yang, Rongqiao
    Li, Baohui
    Shi, An-Chang
    Langmuir, 2012, 28 (02): : 1569 - 1578
  • [2] Phase Behavior of Binary Blends of Diblock Copolymer/Homopolymer Confined in Spherical Nanopores
    Yang, Rongqiao
    Li, Baohui
    Shi, An-Chang
    LANGMUIR, 2012, 28 (02) : 1569 - 1578
  • [3] Phase behavior of ternary homopolymer/diblock blends: Influence of relative chain lengths
    Janert, PK
    Schick, M
    MACROMOLECULES, 1997, 30 (01) : 137 - 144
  • [4] Phase behavior of ternary blends of diblock copolymer with homopolymer blends
    Huh, J
    Jo, WH
    JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (21): : 9920 - 9926
  • [5] Phase Behavior of Binary Blends of Diblock Copolymers
    Wu, Zhuqiang
    Li, Baohui
    Jin, Qinghua
    Ding, Datong
    Shi, An-Chang
    JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (48): : 15789 - 15798
  • [6] MORPHOLOGY DIAGRAM FOR BINARY BLENDS OF HOMOPOLYMER AND DIBLOCK COPOLYMER
    THOMAS, EL
    WINEY, KI
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 150 - PMSE
  • [7] Phase Behavior of Diblock Copolymer-Homopolymer Ternary Blends with a Compositionally Asymmetric Diblock Copolymer
    Zhang, Bo
    Xie, Shuyi
    Lodge, Timothy P.
    Bates, Frank S.
    MACROMOLECULES, 2021, 54 (01) : 460 - 472
  • [8] Phase behavior of ternary homopolymer/diblock blends: Microphase unbinding in the symmetric system
    Janert, PK
    Schick, M
    MACROMOLECULES, 1997, 30 (13) : 3916 - 3920
  • [9] ISOTHERMAL MORPHOLOGY DIAGRAMS FOR BINARY BLENDS OF DIBLOCK COPOLYMER AND HOMOPOLYMER
    WINEY, KI
    THOMAS, EL
    FETTERS, LJ
    MACROMOLECULES, 1992, 25 (10) : 2645 - 2650
  • [10] Pressure and temperature effects in homopolymer blends and diblock copolymers
    Frielinghaus, H
    Schwahn, D
    Mortensen, K
    Willner, L
    Almdal, K
    PHYSICA B-CONDENSED MATTER, 1997, 234 : 260 - 262
12345