Synthesis, cyclic voltammetry, and photophysical properties of a bridged o-phenylenediamine-C60 dyad

被引：12
|
作者：
Diekers, M
Hirsch, A
Luo, CP
Guldi, DM
Bauer, K
Nickel, U
机构：
[1] Inst Organ Chem, D-91054 Erlangen, Germany
[2] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA
[3] Inst Phys Chem, D-91058 Erlangen, Germany
来源：
ORGANIC LETTERS | 2000年 / 2卷 / 18期
关键词：
D O I：
10.1021/ol005992s
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis, complete spectroscopic characterization, cyclic voltammetry, and photophysical measurements of a new omicron-phenylenediamine C-60 dyad are described. By using a tether strategy, only a single regioisomer was obtained. Cyclic voltammetry measurements indicate that the two electroactive groups do not interact in their singlet ground states. Photophysical investigations reveal a rapid photoinduced electron transfer between the singlet excited state of the fullerene acceptor and the omicron-phenylenediamine donor, yielding a charge-separated radical pair.
引用
收藏
页码：2741 / 2744
页数：4
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