Hyperbranched conjugated polyelectrolyte bilayers for solar-cell applications

被引：123

作者：

Taranekar, Prasad ^{[1
]}

Qiao, Qiquan ^{[1
]}

Jiang, Hui ^{[1
]}

Ghiviriga, Ion ^{[1
]}

Schanze, Kirk S. ^{[1
]}

Reynolds, John R. ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 29期

关键词：

DENDRITIC POLYMERS; ELECTRON INJECTION; TIO2; DENDRIMERS; DYE; ETHYNYLENE); PERFORMANCE; LIGHT; STATE; FILMS;

D O I：

10.1021/ja073216a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationically and anionically charged hyperbranched conjugated polyelectrolytes (HB-CPEs) PNMe3+ and PSO3- have been synthesized via the Heck coupling method using A(3) + B-2 type approach. Both HB-CPEs are highly fluorescent and soluble in polar organic solvents allowing processing to electrostatic adsorption. TiO2 hybrid solar cells have been fabricated with the HB-CPEs as sensitizers. The self-assembled bilayer HB-CPE films show higher overall efficiencies when compared to their respective monolayers

引用

页码：8958 / +

页数：3

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