Stable, Well-Defined Nickel(0) Catalysts for Catalytic C-C and C-N Bond Formation

被引：51

作者：

Nett, Alex J. ^{[1
]}

Canellas, Santiago ^{[1
,2
]}

Higuchi, Yuki ^{[1
]}

Robo, Michael T. ^{[1
]}

Kochkodan, Jeanne M. ^{[1
]}

Haynes, M. Taylor, II ^{[1
,3
]}

Kampf, Jeff W. ^{[1
]}

Montgomery, John ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, 930 North Univ Ave, Ann Arbor, MI 48019 USA

[2] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Avda Paisos Catalans 16, E-43007 Tarragona, Spain

[3] Dept Chem & Biochem, 1 Grand Ave, San Luis Obispo, CA 93405 USA

来源：

ACS CATALYSIS | 2018年 / 8卷 / 07期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

precatalyst; amination; reductive coupling; N-heterocyclic carbenes; catalysis; CROSS-COUPLING REACTIONS; HETEROCYCLIC CARBENE; H FUNCTIONALIZATION; COMPLEXES; PRECATALYST; LIGAND; ARYL; AMINATION; CHLORIDES; PALLADIUM;

D O I：

10.1021/acscatal.8b02187

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis and catalytic activity of several classes of NHC-Ni(0) precatalysts stabilized by electron withdrawing alkenes are described. Variations in the structure of fumarate and acrylate ligands modulate the reactivity and stability of the NHC-Ni(0) precatalysts and lead to practical and versatile catalysts for a variety of transformations. The catalytic activity and efficiency of representative members of this class of catalysts have been evaluated in reductive couplings of aldehydes and alkynes and in N-arylations of amines.

引用

页码：6606 / 6611

页数：11

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