A Rapid and Efficient Synthesis of Allyl Iodides from Baylis-Hillman Adducts: A Facile Synthesis of Semiplenamide D

被引：5

作者：

Das, Biswanath ^{[1
]}

Srinivas, Yallamalla ^{[1
]}

Sudhakar, Chithaluri ^{[1
]}

Damodar, Kongara ^{[1
]}

Reddy, Parigi Raghavendar ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

CHEMISTRY LETTERS | 2010年 / 39卷 / 03期

关键词：

MEDIATED STEREOSELECTIVE-SYNTHESIS; (Z)-TRISUBSTITUTED ALKENES; (Z)-ALLYL IODIDES; (E)-ALLYL; BROMIDES; HALIDES; SYSTEM; WATER;

D O I：

10.1246/cl.2010.246

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of Baylis-Hillman adducts with Et3SiH/I-2 in CHCl3 at room temperature afforded the (Z)- and (E)-allyl iodides in stereoselective manner. The products are formed in excellent yields within 5 min. The method has successfully been utilized for synthesis of natural bioactive fatty acid amide, semiplenamide D.

引用

页码：246 / 247

页数：2

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